In silicosearch for novel methane steam reforming catalysts

CFD-simulation of membrane reactor for methane steam reforming

A membrane reactor is a reaction system that provides higher productivity and lower separation cost in chemical reaction processes. In this paper, packed bed catalytic membrane reactor with palladium membrane for methane steam reforming was analyzed both experimentally and numerically. The numerical model consists of a full set of partial differential equations derived from conservation of mass...

Production of hydrogen by unmixed steam reforming of methane

Stepwise methane steam reforming: a route to CO-free hydrogen

A method for the production of clean hydrogen is demonstrated. The process consists of two steps involving the decomposition of methane to CO-free hydrogen and surface carbon in the first step followed by steam gasification of this surface carbon in the second step. This process can be operated in cycles and could be an excellent hydrogen source for fuel cells and other devices or processes req...

CFD modeling and control of a steam methane reforming reactor

This work initially focuses on developing a computational fluid dynamics (CFD) model of an industrialscale steam methane reforming reactor (reforming tube) used to produce hydrogen. Subsequently, we design and evaluate three different feedback control schemes to drive the area-weighted average hydrogen mole fraction measured at the reforming tube outlet ( x̄H outlet 2 ) to a desired set-point va...

Pd/Ga2O3 methanol steam reforming catalysts: Part II: Catalytic selectivity

Structure, morphology and composition of two Pd/Ga2O3 methanol steam reforming catalysts were correlated with the associated activity and selectivity changes in the methanol steam reforming reaction and linked to studies on pure Ga2O3 supports. For both systems, that are, a Pd/Ga2O3 thin film model catalyst and a powder-supported Pd catalyst, we identified a temperature range in which the reduc...